Publications

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40.Disparate Redox Potentials in Mixed Isomer Electrolytes Reduce Voltage Efficiency of Energy Dense Flow Batteries
Davis, C.M.; Waters, S.E.; Robb, B.H.; Thurston, J.R.; Reber, D.; Marshak, M.P.
Batteries2023,9, 573. DOI:

39.Beyond energy density: flow battery design driven by safety and location
Reber, D.; Jarvis, S. R.; Marshak, M. P.
Energy Adv., 2023, 2, 1357–1365. DOI:

38.Sulfonated Diels-Alder Poly(phenylene) Membrane for Efficient Ion-Selective Transport in Aqueous Metalorganic and Organic Redox Flow Batteries
Robb, B. H.; George, T. Y.; Davis, C. M.; Tang Z.; Fujimoto, Cy.; Aziz, M. J.; Marshak, M. P.
J. Electrochem. Soc.2023, 170, 030515. DOI:

37.Stability of highly soluble ferrocyanides at neutral pH for energy-dense flow batteries
Reber, D.; Thurston, J. R.; Beker, M.; Marshak, M. P.
Cell Reports Phys. Sci.2023, 4, 101215. DOI:

36.The role of energy density for grid-scale batteries
Reber, D.; Jarvis, S. R.; Marshak, M. P.
ChemRxiv. 2022. DOI:

35.Realized potential as neutral pH flow batteries achieve high power densities
Robb, B. H.; Waters, S. E.; Saraidaridis, J. D.; Marshak, M. P.
Cell ReportsPhys. Sci.2022, 3, 101118. DOI:

34.Monitoring Ion Exchange Chromatography with Affordable Flame Emission Spectroscopy
Thurston, J. E.; Marshak, M. P.; Reber, D.
J. Chem. Educ.2022, 99,4051–4056. DOI:

33.Maximizing Vanadium Deployment in Redox Flow Batteries Through Chelation
Waters, S. E.; Davis, C. M.; Thurston, J. E.; Marshak, M. P.
J. Am. Chem. Soc.2022, 144,17753–17757. DOI:

32.High Energy Density Chelated Chromium Flow Battery Electrolyte at Neutral pH
Robb, B. H.; Waters, S. E.; Marshak, M. P.
Chem Asian J. 2022, 17, e202200700.DOI:

31.Transport of Ligand Coordinated Iron and Chromium through Cation-Exchange Membranes
Saraidaridis, J. D.; Darling, R. M.;Yang, Z.;Fortin, M. E.;Shovlin, C.; Robb, B. H.;Waters, S. E.;Marshak, M. P.
J. Electrochem. Soc.2022,169,060532. DOI:

30.Isolation and characterization of a highly reducing aqueous chromium (II) complex
Waters, S.E.; Robb, B. H.; Scappaticci, S. J.; Saraidaridis, J. D.; Marshak, M. P.
Inorg. Chem.2022,61, 8752–8759. DOI:

29.Mediating anion-cation interactions to improve aqueous flow battery electrolytes
Reber, D.; Thurston, J. R.; Becker, M.; Pache, G. F.; Wagoner, M. E.; Robb, B. H.; Waters, S. E.; Marshak, M. P.
Appl. Mater. Today2022,28,101512. DOI:

28.Bismuth Electrocatalyst Enabling Reversible Redox Kinetics of a Chelated Chromium Flow Battery Anolyte
Proctor, A. D.; Robb, B. H.; Saraidaridis, J. D.; Marshak, M. P.
J. Electrochem. Soc.2022, 169,030506. DOI:

27.Holistic design principles for flow batteries: Cation dependent membrane resistance and active species solubility
Waters, S. E.;Thurston, J. R.; Armstrong, R. W.; Robb, B. H.;Marshak, M. P.; Reber, D.
J. Power Sources2022,520, 230877. DOI:

26.Iron Flies Higher
Marshak, M. P.
NatureEnergy2021,6, 854–855. DOI:

25.Synthesis, reactivity, and crystallography of a sterically hindered acyl triflate
Crossman, A. S.; Shi, J. X.; Krajewski, S. M.; Maurer, L. M.; Marshak, M.P.
Tetrahedron2021.94,132308. DOI:
*2021 Editors’ Choice Collection

24.Open for bismuth: main group metal-to-ligand charge transfer
Maurer, L. M.; Pearce, O. M.; Maharaj, F. D. R; Brown, N. L.; Amador, C. A.; Damrauer, N. H.; Marshak, M. P.
Inorg. Chem.2021.60, 10137–10146 DOI:

23.Organic and Metal-Organic RFBs
Thurston, J. R.; Waters, S. E.; Robb, B. H.; Marshak, M.P
Encyclopedia of Energy Storage2021. DOI:

22. β-Diketones: Coordination and Application
Crossman, A. S. and Marshak, M. P.
Comprehensive Coordination Chemistry III.2021, DOI:

21. Evaluating Aqueous Flow Battery Electrolytes: A Coordinated Approach
Robb, B. H.; Waters, S. E.; Marshak, M. P.
Dalton Trans.,2020, 49, 16047–16053. DOI:

20.Minimizing Oxygen Permeation in Metal-Chelate Flow Batteries
Robb, B. H.; Waters, S. E.; Marshak, M. P.
ECS Trans.2020,97, 237–245. DOI:

19.Effect of Chelation on Iron-Chromium Redox Flow Batteries
Waters, S. E.; Robb, B. H.; Marshak, M. P.
ACS Energy Lett.2020,6,1758–1762. DOI:

18.Group 4 Organometallics Supported by Sterically Hindered β‐Diketonates
Hopkins, E. J.; Krajewski, S. M.; Crossman, A. S.; Maharaj, F. D. R.; Schwanz, L. T.; Marshak, M. P.
Eur. J. Inorg. Chem.2020, 20, 1951–1959. DOI:

17.Titanium-Anthraquinone Material as a New Design Approach for Electrodes in Aqueous Rechargeable Batteries
Maharaj, F. D. R.; Marhsak, M. P.
Energies, 2020, 13, 1722. DOI:

16.Copper(II) as a Platform for Probing the Steric Demand of Bulky β-Diketonates
Larson, A. T.; Crossman, A. S.; Krajewski, S. M.; Marshak, M. P.
Inorg. Chem.2020,59, 423–432. DOI:

15.Chelated Chromium Electrolyte Enabling High-Voltage Aqueous Flow Batteries
Robb, B. H.; Farrell, J. M.; Marshak, M. P.
Joule,2019. 3, 2503–2512. DOI:

14.Sterically encumbered β-diketonates and base metal catalysis
Krajewski, S. M.; Crossman, A. S.; Akturk, E. S.; Suhrbier, T.; Scappaticci, S. J.; Staab, M. W.; Marshak, M. P.
Dalton Trans.2019.48, 10714–10722. DOI:

13.Exploring Real-World Applications of Electrochemistry by Constructing a Rechargeable Lithium Ion Battery
Maharaj, F. D. R.; Wu, W.; Zhou, Y,; Schwanz, L. T.; Marshak, M. P.
J. Chem. Educ.2019,96, 3014–3017.DOI:

12.Synthesis of Sterically Hindered β-Diketones via Condensation of Acid Chlorides with Enolates
Crossman, A. S.; Larson, A. T.; Shi, J. X.; Krajewski, S. M.; Akturk, E. S.; Marshak, M. P.
J. Org. Chem. 2019. 84, 7434–7442. DOI:

11.Bulky β-Diketones Enabling New Lewis Acidic Ligand Platforms
Akturk, E. S.; Scappaticci, S. J.; Seals, R. N.; Marshak, M. P.
Inorg. Chem.2017. 56, 11466–11469. DOI:

10. My trek back to science
Marshak, M. P.
Science2015,349, 1406.DOI:

Prior to CU

9.Anthraquinone Derivatives in Aqueous Flow Batteries
Gerhardt, M. R.; Tong, L.;Gómez‐Bombarelli, R.; Chen, Q.; Marshak, M. P.; Galvin, C. J.; Aspuru-Guzik, A.; Gordon, R. G.; Aziz, M. J.
Adv. Energy Mater.2017.7, 1601488. DOI:

8.Alkaline quinone flow battery
Lin, K.; Chen, Q.; Gerhardt, M. R.; Tong, L.; Kim, S. B.; Eisenach, L.; Valle, A. W.; Hardee, D.; Gordon, R. G.; Aziz, M. J.; Marshak, M. P.
Science2015, 349, 1529–1532. DOI:

7. Computational design of molecules for an all-quinone redox flow battery
Er, S.; Suh, C.; Marshak, M. P.; Aspuru-Guzik, A.
Chem. Sci.2015,6, 885–893.​DOI:

6. Cycling of a Quinone-Bromide Flow Battery for Large-Scale Electrochemical Energy Storage
Huskinson, B.; Marshak, M. P.; Gerhardt, M. R.; Aziz, M. J.
ECS Trans.2014,61, 27–30.DOI:

5.A metal-free organic-inorganic aqueous flow battery
Huskinson, B.; Marshak, M. P.; Suh, C.; Er, S.; Gerhardt, M. R.; Galvin, C. J.; Chen, X.; Aspuru-Guzik, A.; Gordon, R. G.; Aziz, M. J.
Nature2014,505, 195–198.DOI:

4. Lewis Bases Trigger Intramolecular CH–Bond Activation: (tBu3SiO)2W=NtBu [rlhar2] (tBu3SiO)(κO,κC-tBu2SiOCMe2CH2)HW=NtBu
Marshak, M. P.; Rosenfeld, D. C.; Morris, W. D.; Wolczanski, P. T.; Lobkovsky, E. B.; Cundari, T. R.
Eur. J. Inorg. Chem.2013,4056–4067.DOI:

3. Chromium(IV) Siloxide
Marshak, M. P.; Nocera, D. G.
Inorg. Chem.2013,52, 1173–1175.DOI:

2. Cobalt in a Bis-β-diketiminate Environment
Marshak, M. P.; Chambers, M. B.; Nocera, D. G.
Inorg. Chem.2012,51, 11190–11197.DOI:

1. Thermodynamics, Kinetics, and Mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) Rearrangements (silox = tBu3SiO; M = Nb, Ta)
Hirsekorn, K. F.; Veige, A. S.; Marshak, M. P.; Koldobskaya, Y.; Wolczanski, P. T.; Cundari, T. R.; Lobkovsky, E. B.
J. Am. Chem. Soc.2005,127, 4809–4830.DOI: